Efficient electro/photocatalytic water reduction using a [NiII(N2Py3)]2+ complex.
نویسندگان
چکیده
The pyridine-rich complex [NiII(LN2Py3)(MeCN)](ClO4)2 (1) acts as an efficient electro- and photocatalyst in the generation of H2 from water. Observed TONs reach 1050 for electrocatalysis and a remarkable 3500 for photocatalysis. Experimental and DFT data support the ligand-reduced [NiIL˙] as the catalytically active species, contrasting with the [CoIL] observed for cobalt catalysts.
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ورودعنوان ژورنال:
- Chemical communications
دوره 52 91 شماره
صفحات -
تاریخ انتشار 2016